Sustainable Hydrogen Production through Steam Methane Reforming and Water Electrolysis – A Review
DOI:
https://doi.org/10.48039/mjtum.v4i2.101Keywords:
Green energy, Hydrogen production, Methane reforming, Water electrolysis, Catalytic activityAbstract
Nearly half of the hydrogen produced worldwide comes from the most popular and economical method of hydrogen synthesis, methane steam reforming (MSR). However, there are a number of challenges that must be conquered before MSR can be widely used, despite the fact that it is a well-established technique. The primary research gaps in the MSR process center around improving the catalyst longevity and efficiency, addressing the process's high energy consumption and carbon emissions, and enabling cost-effective small-scale hydrogen production. As an alternative, electrolysis of water could yield pure hydrogen. Nevertheless, hydrogen production from water electrolysis is synonymous with high costs (electricity, capital), as well as obstacles like the synthesis of more affordable and effective catalysts for the procedure, enhancing system intergration with renewables, and achieving true large scale manufacturing and scalability. In this review paper, both processes have been critically analyzed to give insights into current processes, the challenges faced, and prospects. Since both methane steam reforming and water electrolysis generate valuable hydrogen, optimization of the two could offer a more sustainable and reliable source of energy.
References
Angeles-Olvera, Z., Crespo-Yapur, A., Rodríguez, O., Cholula-Díaz, J.L., Martínez, L.M., & Videa, M. (2022). Nickel-Based Electrocatalysts for Water Electrolysis. Energies, 15(5): 35 doi:https://doi.org/10.3390/en15051609
Anwar, S., Khan, F., Zhang, Y., & Djire, A. (2021). Recent development in electrocatalysts for hydrogen production through water electrolysis. International Journal of Hydrogen Energy, 46(63): 32284-32317 doi:https://doi.org/10.1016/j.ijhydene.2021.06.191
Arutyunov, V., Savchenko, V., Sedov, I., Arutyunov, A., & Nikitin, A. (2022). The Fuel of Our Future: Hydrogen or Methane? MDPI - Methane, 1(2): 96-106 doi:https://doi.org/10.3390/methane1020009
Bengaard, H.S., Nørskov, J.K., Sehested, J., Clausen, B.S., Nielsen, L. P., Molenbroek, A.M., & Rostrup-Nielsen, J.R. (2002). Steam Reforming and Graphite Formation on Ni Catalysts. Journal of Catalysis, 209(2): 365-384. doi:https://doi.org/10.1006/jcat.2002.3579
Brauns, J., & Turek, T. (2020). Alkaline Water Electrolysis Powered by Renewable Energy: A Review. MDPI - Processes, 8(2), 248 doi:https://doi.org/10.3390/pr8020248
Chorkendorff, I., & Niemantsverdriet, J.W. (2017). Concepts of Modern Catalysis and Kinetics: Wiley.
Council, N. R., & Engineering, N.A.O. (2004). The Hydrogen Economy: Opportunities, Costs, Barriers, and Ramp D Needs. Washington, DC: The National Academies Press.
Farshchi Tabrizi, F., Mousavi, S.A.H. S., & Atashi, H. (2015). Thermodynamic analysis of steam reforming of methane with statistical approaches. Energy Conversion and Management, 103: 1065-1077 doi:https://doi.org/10.1016/j.enconman.2015.07.005
Hauch, A., Küngas, R., Blennow, P., Hansen, A. B., Hansen, J.B., Mathiesen, B.V., & Mogensen, M.B. (2020). Recent advances in solid oxide cell technology for electrolysis. Science, 370(6513), eaba6118. doi:https://doi.org/10.1126/science.aba6118
Ib, A., Rostrup-Nielsen, J.R., & Røen, S. (1981). High temperature hydrogen sulfide chemisorption on nickel catalysts. Applied Catalysis, 1, 303-314. doi:https://doi.org/10.1016/0166-9834(81)80036-X
Kovač, A., Marciuš, D., & Budin, L. (2019). Solar hydrogen production via alkaline water electrolysis. International Journal of Hydrogen Energy, 44(20), 9841-9848. doi:https://doi.org/10.1016/j.ijhydene.2018.11.007
Lavoie, J.M. (2014). Review on dry reforming of methane, a potentially more environmentally-friendly approach to the increasing natural gas exploitation. Front Chem, 2. doi:https://doi.org/10.3389/fchem.2014.00081
Lee, S. (2013). Concepts in Syngas Manufacture. By Jens Rostrup-Nielsen and Lars J. Christiansen. Energy Technology, 1(7), 419-420. doi:https://doi.org/10.1002/ente.201305007
Li, Y., Yang, G., Yu, S., Kang, Z., Mo, J., Han, B., . . Zhang, F.Y. (2019). In-situ investigation and modeling of electrochemical reactions with simultaneous oxygen and hydrogen microbubble evolutions in water electrolysis. International Journal of Hydrogen Energy, 44(52): 28283-28293 doi:https://doi.org/10.1016/j.ijhydene.2019.09.044
Liu, Z., Han, B., Lu, Z., Guan, W., Li, Y., Song, C., . . . Singhal, S.C. (2021). Efficiency and stability of hydrogen production from seawater using solid oxide electrolysis cells. Applied Energy, 300, 117439. doi:https://doi.org/10.1016/j.apenergy.2021.117439
Marzouk, O.A. (2024). Expectations for the Role of Hydrogen and Its Derivatives in Different Sectors through Analysis of the Four Energy Scenarios: IEA-STEPS, IEA-NZE, IRENA-PES, and IRENA-1.5°C. MDPI - Energies, 17(3), 646. doi:https://doi.org/10.3390/en17030646
Milewski, J., Kupecki, J., Szczęśniak, A., & Uzunow, N. (2021). Hydrogen production in solid oxide electrolyzers coupled with nuclear reactors. International Journal of Hydrogen Energy, 46(72):35765-35776 doi:https://doi.org/10.1016/j.ijhydene.2020.11.217
Ming, M., Zhang, Y., He, C., Zhao, L., Niu, S., Fan, G., & Hu, J.-S. (2019). Room-Temperature Sustainable Synthesis of Selected Platinum Group Metal (PGM = Ir, Rh, and Ru) Nanocatalysts Well-Dispersed on Porous Carbon for Efficient Hydrogen Evolution and Oxidation. NANO - MICRO small, 15(49): 1903057. doi:https://doi.org/10.1002/smll.201903057
Richter, J., Rachow, F., Israel, J., Roth, N., Charlafti, E., Günther, V., . . . Mauss, F. (2023). Reaction Mechanism Development for Methane Steam Reforming on a Ni/Al2O3 Catalyst. MDPI - Catalysts, 13(5): 884. doi:https://doi.org/10.3390/catal13050884
Rosen, M.A. (1991). Thermodynamic investigation of hydrogen production by steam-methane reforming. International Journal of Hydrogen Energy, 16(3), 207-217. doi:https://doi.org/10.1016/0360-3199(91)90003-2
Rostrup-Nielsen, J., & Christiansen, L.J. (2011). Concepts In Syngas Manufacture: World Scientific Publishing Company.
Saha, P., Akash, F.A., Shovon, S.M., Monir, M.U., Ahmed, M.T., Khan, M.F.H., . . . Akter, R. (2024). Grey, blue, and green hydrogen: A comprehensive review of production methods and prospects for zero-emission energy. International Journal of Green Energy, 21(6), 1383-1397. doi:https://doi.org/10.1080/15435075.2023.2244583
Salonen, L.M., Petrovykh, D.Y., & Kolen'ko, Y.V. (2021). Sustainable catalysts for water electrolysis: Selected strategies for reduction and replacement of platinum-group metals. Materials Today Sustainability, 11-12: 100060. doi:https://doi.org/10.1016/j.mtsust.2021.100060
Sapountzi, F.M., Gracia, J.M., Weststrate, C.J., Fredriksson, H.O.A., & Niemantsverdriet, J.W. (2017). Electrocatalysts for the generation of hydrogen, oxygen and synthesis gas. Progress in Energy and Combustion Science, 58,1-35 doi:https://doi.org/10.1016/j.pecs.2016.09.001
Schulz, L.A., Kahle, L.C.S., Delgado, K.H., Schunk, S.A., Jentys, A., Deutschmann, O., & Lercher, J. A. (2015). On the coke deposition in dry reforming of methane at elevated pressures. Applied Catalysis A: General, 504, 599-607. doi:https://doi.org/10.1016/j.apcata.2015.03.002
Kumar, S., & Himabindu, V. (2019). Hydrogen production by PEM water electrolysis – A review. Materials Science for Energy Technologies, 2(3), 442-454. doi:https://doi.org/10.1016/j.mset.2019.03.002
Shiva Kumar, S., & Lim, H. (2022). An overview of water electrolysis technologies for green hydrogen production. Energy Reports, 8, 13793-13813. doi:https://doi.org/10.1016/j.egyr.2022.10.127
Smolinka, T. (2009). FUELS – HYDROGEN PRODUCTION | Water Electrolysis. In J. Garche (Ed.), Encyclopedia of Electrochemical Power Sources (pp. 394-413). Amsterdam: Elsevier.
Taifan, W., & Baltrusaitis, J. (2017). Minireview: direct catalytic conversion of sour natural gas (CH4 + H2S + CO2) components to high value chemicals and fuels. Catalysis Science & Technology, 7(14), 2919-2929. doi:https://doi.org/10.1039/C7CY00272F
Wang, Q., Wang, H., Cao, H., Tung, C.-W., Liu, W., Hung, S.-F., . . . Liu, B. (2023). Atomic metal–non-metal catalytic pair drives efficient hydrogen oxidation catalysis in fuel cells. Nature Catalysis, 6(10), 916-926. doi:https://doi.org/10.1038/s41929-023-01017-z
Wang, S., Lu, A., & Zhong, C.-J. (2021). Hydrogen production from water electrolysis: role of catalysts. Nano Convergence, 8(1), 4. doi:https://doi.org/10.1186/s40580-021-00254-x
Wang, T., Cao, X., & Jiao, L. (2022). PEM water electrolysis for hydrogen production: fundamentals, advances, and prospects. Carbon Neutrality, 1(1), 21. doi:https://doi.org/10.1007/s43979-022-00022-8
Wu, H., Feng, C., Zhang, L., Zhang, J., & Wilkinson, D. P. (2021). Non-noble Metal Electrocatalysts for the Hydrogen Evolution Reaction in Water Electrolysis. Electrochemical Energy Reviews, 4(3), 473-507. doi:https://doi.org/10.1007/s41918-020-00086-z
Yoo, J., Bang, Y., Han, S. J., Park, S., Song, J. H., & Song, I. K. (2015). Hydrogen production by tri-reforming of methane over nickel–alumina aerogel catalyst. Journal of Molecular Catalysis A: Chemical, 410, 74-80. doi:https://doi.org/10.1016/j.molcata.2015.09.008
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Mwadhi William Mulewa , Machandi Joseph Mbothu , Fwedeha Elvis Makonde

This work is licensed under a Creative Commons Attribution 4.0 International License.


